To set NTP Peers for the Windows Time Service, enter the following at an elevated command prompt
w32tm /config /update /manualpeerlist:"0.pool.ntp.org 1.pool.ntp.org 2.pool.ntp.org" /syncfromflags:manual
Check the status of the NTP Peers with these commands
w32tm /query /peers w32tm /query /status
This is to sync with any other NTP time servers besides your local domain controller.